1. Innovene usoro
Isi ihe dị na usoro Innovene bụ iji ihe pụrụ iche dị nso-plug eruba kehoraizin kpalitere ihe ntanye ihe ndina nke nwere ihe ndị na-eme ka ọ dị n'ime ya na ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ bụrụ ihe na-eme ka ọ dị mma, a na-atụgharị agụba na-akpali akpali na 45 ° na ogwe aka na-akpali akpali, nke nwere ike gbanwee ihe ndina ahụ dum. .A na-eme mkpali nwayọ na mgbe niile.Enwere ọtụtụ ihe nri gas na mmiri mmiri n'ime akwa mmeghachi omume nke a na-enye nri, propylene mmiri na gas.The obibi oge nkesa n'ihi nke a reactor imewe bụ Ẹkot 3 ezigbo kpaliri tankị The ụdị reactors jikọọ na usoro, otú ika ịmafe bụ nnọọ ngwa ngwa, na mgbanwe ihe dị nnọọ obere.Usoro a na-agbaso usoro nke propylene flash evaporation iji wepụ okpomọkụ.
Tụkwasị na nke ahụ, usoro ahụ na-eji usoro mkpuchi ikuku, nke nwere ike mechie ngwa ngwa na nke ọma site n'ịkwụsị ịgba ọgwụ mgbochi, ma malitegharịa mgbe nkwụsịtụ na nkwụsịtụ.N'ihi nhazi pụrụ iche, usoro ahụ nwere ike oriri kachasị ala na nrụgide ọrụ nke usoro ọ bụla , naanị ihe ọjọọ bụ na ọnụ ọgụgụ dị ukwuu nke ethylene (ma ọ bụ akụkụ nke ihe ndị na-emepụta roba) na ngwaahịa adịghị elu, na ngwaahịa nke ultra. -enweghi ike inweta akara ugo mmetụta dị elu.
Ngwunye agbaze agbaze (MFR) nke ngwaahịa homo-polymerized nke usoro Innovene dị oke obosara, nke nwere ike iru 0.5 ~ 100g / 10min, na ngwaahịa siri ike dị elu karịa nke enwetara site na usoro polymerization gas ndị ọzọ;MFR nke ngwaahịa co-polymerization random bụ 2 ~ 35g / 10min, ọdịnaya ethylene bụ 7% ~ 8%;MFR nke ngwaahịa co-polymer mmetụta bụ 1 ~ 35g / 10min, yana akụkụ ethylene mass bụ 5% ~ 17%.
2. Usoro Novolen
Usoro Novolen na-anabata reactors vetikal abụọ na-akpalite okpukpu abụọ, nke na-eme ka nkesa gas siri ike nke abụọ na gas-phase polymerization dịtụ otu, na-ewepụ okpomọkụ nke polymerization site na vaporization nke propylene mmiri mmiri.The homo-polymerization na The co-polymerization nakweere gas na-emepụta polymerization, na ihe pụrụ iche ya bụ na a pụrụ imepụta homo-polymer site na onye na-emepụta ihe na-emepụta ihe na-emepụta ihe (n'usoro na mbụ homo-polymerization reactor), nke nwere ike ịbawanye mkpụrụ. nke homo-polymer site na 30%.N'otu aka ahụ, a pụkwara iji ndị na-emepụta ihe na-emepụta ihe.A na-emepụta mmepụta site na ijikọ reactors na usoro.
Usoro Novolen nwere ike ịmepụta ngwaahịa niile gụnyere homo-polymer, random co-polymers, impact co-polymer, super impact co-polymer, wdg MFR nso nke ulo oru PP homo-polymer grades bụ 0.2 ~ 100g / 10min, random co- polymerization Nke kachasi elu uka ethylene na ngwaahịa bụ 12%, na uka nke ethylene na-emepụta mmetụta co-polymer nwere ike iru 30% (oke nta nke roba bụ 50%).Ọnọdụ mmeghachi omume maka imepụta mmetụta co-polymer bụ 60 ~ 70 ℃, 1.0 ~ 2.5MPa.
3. Usoro Unipol
The Unipol usoro reactor bụ cylindrical vetikal vetikal arịa nwere nnukwu elu dayameta, nke nwere ike na-arụ ọrụ na a supercondensed steeti, nke a na-akpọ supercondensed steeti gas-phase fluidized bed process (SCM).
MFR nke homo-polymer nke ụlọ ọrụ mmepụta ihe na-emepụta site na usoro Unipol bụ 0.5 ~ 100g / 10min, na ọnụ ọgụgụ dị ukwuu nke ethylene comonomer na random co-polymer nwere ike iru 5.5%;na random co-polymer nke propylene na 1-butene e ulo oru (ahia aha CE -FOR), nke uka nta nke roba nwere ike ịdị elu dị ka 14%;Ọnụ ọgụgụ dị nta nke ethylene na mmetụta co-polymer nke usoro Unipol na-emepụta nwere ike iru 21% (oke nke rubber bụ 35%).
4. Horizon Craft
The Horizone usoro na-mepụtara na ndabere nke Innovene gas na-adọ usoro technology, na e nwere ọtụtụ myirịta n'etiti abụọ, karịsịa chernobyl imewe bụ ihu ọma otu.
Isi ihe dị iche n'etiti usoro abụọ ahụ bụ na a na-ahazi reactors abụọ nke usoro Horizone n'ụzọ kwụ ọtọ na ala, mmepụta nke reactor nke mbụ na-abanye ozugbo n'ime ngwaọrụ mkpuchi ikuku site na ike ndọda, wee tinye ya na reactor nke abụọ na nrụgide propylene. ;mgbe mmeghachi omume abụọ nke usoro Innovene A na-ahazi ndị na-emepụta ihe n'otu n'otu na nha anya, na mmepụta nke mbụ reactor na-ebu ụzọ zigara onye ọbịa ahụ n'ebe dị elu, na ntụ ntụ polymer kewapụrụ na-enye nri n'ime mkpọchi ikuku site na ike ndọda, wee ziga ya na reactor nke abụọ site na nrụgide propylene.
E jiri ya tụnyere abụọ ahụ, usoro Horizone dị mfe na imewe ma na-eri obere ume.Tụkwasị na nke ahụ, ihe na-akpali akpali nke a na-eji na Horizone usoro kwesịrị ka a na-emezi ya, nke a na-eme ka ọ bụrụ slurry na hexane, na obere propylene na-agbakwunye maka prepolymerization, ma ọ bụghị ya, ezigbo ntụ ntụ dị na ngwaahịa ahụ ga-abawanye, mmiri mmiri ga-ebelata. na ọrụ nke co-polymerization reactor ga-esi ike.
Usoro Horizone gas na-aga PP nwere ike ịmepụta ngwaahịa dị iche iche.Ụdị MFR nke ngwaahịa homo-polymer bụ 0.5 ~ 300g / 10min, yana akụkụ ethylene mass nke co-polymers random ruru 6%.The MFR nke mmetụta co-polymer ngwaahịa bụ 0.5 ~ 100g / 10min, ọnụ ọgụgụ dị nta nke roba dị elu dị ka 60%.
5. Usoro Spheripol
Usoro Spheripol na-anabata usoro mmiri mmiri nke nnukwu gas na-ejikọta usoro, a na-eji mmiri mmiri loop reactor eme ihe maka prepolymerization na mmeghachi omume homo-polymerization, yana gas na-eme ihe na-eme ihe n'ihe ndina ga-eji maka mmeghachi omume co-polymerization multiphase.Enwere ike kewaa ya n'otu mgbanaka dịka ike mmepụta na ụdị ngwaahịa.Enwere ụdị mmeghachi omume polymerization anọ, ya bụ, mgbanaka abụọ, mgbanaka abụọ na otu gas, na mgbanaka abụọ na gas abụọ.
Ọgbọ nke abụọ Spheripol usoro na-anabata usoro nke ọgbọ nke anọ, na imewe nrụgide larịị nke prepolymerization na polymerization reactors na-abawanye, nke mere na arụmọrụ nke ọhụrụ ika dị mma, na-arụ ọrụ nke ochie ika na-mma, na ya. bụkwa ihe na-enye aka na morphology, isotacticity na ikwu.Njikwa oke nke molecular.
Usoro ngwaahịa nke Spheripol dị obosara nke ukwuu, MFR bụ 0.1 ~ 2 000g / 10min, ọ nwere ike ịmepụta ngwaahịa PP zuru oke, gụnyere PP homo-polymer, random co-polymers na terpolymers, mmetụta co-polymers na heterogeneous mmetụta Co. -polymers, random co-polymers nwere ike iru 4.5% ethylene, mmetụta co-polymers nwere ike iru 25%-40% ethylene, na roba na-adọ nwere ike iru 40%-60%.
6. Usoro Hypol
Usoro Hypol na-anakwere teknụzụ usoro nke tubular liquid phase nnukwu gas na-ejikọta usoro, na-eji usoro TK-II nke nrụpụta ọrụ dị elu, ma na-eji usoro Hypol II ugbu a.
Isi ihe dị iche n'etiti usoro Hypol II na usoro Spheripol bụ imewe nke gas na-arụ ọrụ reactor, na nkeji ndị ọzọ gụnyere catalyst na prepolymerization bụ otu ihe ahụ dị ka usoro Spheripol.Usoro Hypol II na-eji onye na-eme ihe ike nke ise (RK-catalyst), nke nwere ọrụ kachasị elu Ọrụ nke ọgbọ nke anọ bụ 2-3 ugboro dị elu karịa nke ọgbọ nke anọ, nke nwere nnukwu hydrogen modulation sensitivity. ma nwee ike imepụta ngwaahịa nwere oke MFR buru ibu.
Usoro Hypol II na-eji 2 loop reactors na gas na-emepụta ihe na-eme ihe na-eme ihe na-eme ihe na-eme ihe na-eme ka ọ bụrụ ihe na-akpali akpali iji mepụta homopolymers na mmetụta copolymers, nke abụọ reactor bụ gas na-eme ihe na-eme ihe na-eme ka ihe ndina na-eme ihe na-eme ka ọ bụrụ ihe na-akpali akpali Ọnọdụ mmeghachi omume nke onye na-emegharị ihe na HypolII. usoro bụ 62 ~ 75 ℃, 3.0 ~ 4.0MPa, na mmeghachi omume ọnọdụ maka mmepụta nke mmetụta copolymers bụ 70 ~ 80 ℃, 1.7 ~ 2.0MPa.Usoro HypolII nwere ike ịmepụta homopolymers, ọ dịghị mgbe ọ bụla copolymer na ngọngọ copolymer, MFR nso nke ngwaahịa bụ 0.3 ~ 80g / 10min.The homopolymer kwesịrị ekwesị maka mmepụta nke transperent film, monofilament, teepu na eriri, na copolymer nwere ike iji maka mmepụta nke ezinụlọ ngwa, ụgbọala na ụlọ ọrụ akụkụ na components.Obere okpomọkụ na ngwaahịa dị elu.
7. Usoro Spherzone
Usoro Spherizone bụ ọgbọ ọhụrụ nke teknụzụ mmepụta PP nke LyondellBasell mepụtara na ndabere nke usoro Spheripol I.
A na-ekewa reactor na-ekesa ọtụtụ mpaghara na mpaghara mmeghachi omume abụọ: ngalaba na-arịgo na ngalaba na-agbada.Ihe ndị ahụ polymer na-ekesa na mpaghara mmeghachi omume abụọ ruo ọtụtụ oge.A na-eme ka ihe ndị dị na polymer dị na mpaghara na-arịgo ngwa ngwa n'okpuru ọrụ nke gas na-ekesa ma banye na cyclone n'elu akụkụ nke na-agbada.A na-eme nkewa, nkewa siri ike gas na nkewa nke cyclone.Enwere ebe mgbochi n'elu akụkụ nke na-agbadata iji kewaa gas mmeghachi omume na ihe polymer.Ihe irighiri ihe na-agbada na ala nke ngalaba na-agbada wee banye na ngalaba na-arịgo iji mezue okirikiri.Mpaghara mgbochi Ojiji nke reactor nwere ike ghọta ọnọdụ mmeghachi omume dị iche iche nke ngalaba arịgoro na ngalaba na-agbada, wee mepụta mpaghara mmeghachi omume abụọ dị iche iche.
8. Sinopec loop pipe usoro
Na ndabere nke mgbari na ịnara teknụzụ ebubatara, Sinopec emebela nke ọma na usoro PP na teknụzụ injinịa nke ọma.N'iji ihe na-emepụta ZN nke na-emepụta onwe ya, a na-ahazi monomer propylene na polymerized iji mepụta ngwaahịa homo-polymeric isotactic PP, propylene Ọ na-emepụta mmetụta PP ngwaahịa site na-emekọ ihe ọnụ ma ọ bụ igbochi co-polymerization na comonomers, na-eme ka ọgbọ mbụ PP zuru oke. teknụzụ nke 70,000 ruo 100,000 t/a.
Na ndabere nke a, ọgbọ nke abụọ loop PP zuru ezu usoro teknụzụ nke 200,000 t / gas-phase reactor ka emepụtara, nke nwere ike ịmepụta ngwaahịa nkesa bimodal na mmetụta dị elu co-polymers.
Na 2014, Sinopec's "Ten-train" research oru - "ọgbọ nke atọ gburugburu gburugburu ebe obibi PP zuru ezu technology mmepe" jikọrọ ọnụ nke Sinopec Beijing Chemical Research Institute, Sinopec Wuhan Alaka na Sinopec Huajiazhuang Refining na Chemical Alaka gafere The teknuzu nyocha haziri. Ụgwọ nke ụlọ ọrụ China Petrochemical CorporationTeknụzụ a zuru oke dabere na ihe nrụpụta nke mepụtara onwe ya, teknụzụ enyemaka elektrọn mpụga asymmetric na teknụzụ propylene-butylene nwere akụkụ abụọ nke random co-polymerization, wee mepụta loop ọgbọ nke atọ PP zuru oke nke teknụzụ.Enwere ike iji teknụzụ a mepụta homo-polymerization, ethylene-propylene random co-polymerization, propylene-butylene random co-polymerization na mmetụta na-eguzogide co-polymer PP, wdg.
